Size Dependence of the Energetics of Electron Attachment to Large Water Clusters
نویسندگان
چکیده
The size dependence of the binding energy of a localized excess electron in large water clusters originates from long-range polarization interactions. The vertical and adiabatic binding energies of compact, interior excess electron states in (H20); clusters, obtained from quantum path-integral moleculardynamics simulations, exhibit a linear dependence on n I/‘, in quantitative agreement with the implications of dielectric medium effects in finite systems.
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